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Oxone® - Monopersulfate Compound - 100 Gr - Sigma

Código: 19417

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OXONE®, monopersulfate compound

Sinônimo(s):

Potassium peroxymonosulfate

Fórmula linear:

KHSO5 · 0.5KHSO4 · 0.5K2SO4

Número CAS:

70693-62-8

Peso molecular:

307.38

Número MDL:

MFCD00040551

ID de substância PubChem:

57648006

NACRES:

NA.21

pressão de vapor

 

Nível de qualidade

200

forma

powder

reaction suitability

reagent type: oxidant

concentração

>4.0% (active oxygen basis (by Na2S2O3, titration))

pH

2.1 (77 °C, 30 g/L)

SMILES string

[K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O

InChI

1S/5K.2H2O5S.2H2O4S/c;;;;;2*1-5-6(2,3)4;2*1-5(2,3)4/h;;;;;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5

InChI key

HJKYXKSLRZKNSI-UHFFFAOYSA-I

Descrição geral

OXONE®, monopersulfate compound is a potassium triple salt mainly used as a stable, easy to handle and nontoxic oxidant.[1]

Aplicação

A rapid, efficient synthesis of oxaziridines from imines using buffered OXONE has been reported.[2] Also used to study fading of an artist′s colorants.[3]

OXONE®, monopersulfate compound may be used as an alternative to transition-metal oxidants for the conversion of aldehydes to carboxylic acids or esters.[1]

Oxidant used for halogenation of α,β-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation.

Oxidant used for halogenation of a,b-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation.

2-Iodoxybenzenesulfonic Acid as an Extremely Active Catalyst for the Selective Oxidation of Alcohols to Aldehydes, Ketones, Carboxylic Acids, and Enones with Oxone

A Convenient Halogenation of α,β-Unsaturated Carbonyl Compounds with OXONE® and Hydrohalic Acid (HBr, HCl)

Informações legais

OXONE is a registered trademark of E. I. du Pont de Nemours and Company

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