(R)-(−)-Carvone

98%

Sinônimo(s):

(−)-Carvone, (R)-5-Isopropenyl-2-methyl-2-cyclohexenone, p-Mentha-6,8-dien-2-one, Carvol

Sobre este item

Fórmula empírica (Notação de Hill):

C₁₀H₁₄O

Número CAS:

6485-40-1

Peso molecular:

150.22

Beilstein:

2206714

Número CE:

229-352-5

Número MDL:

MFCD00001578

Código UNSPSC:

12352115

ID de substância PubChem:

24847635

NACRES:

NA.22

densidade de vapor

5.2 (vs air)

Nível de qualidade

100

pressão de vapor

0.4 mmHg ( 20 °C)

Ensaio

98%

Formulário

liquid

atividade óptica

[α]20/D −61°, neat

índice de refração

n20/D 1.497 (lit.)

p.e.

227-230 °C (lit.)

densidade

0.959 g/mL at 25 °C (lit.)

grupo funcional

ketone

cadeia de caracteres SMILES

CC(=C)[C@@H]1CC=C(C)C(=O)C1

InChI

1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m1/s1

chave InChI

ULDHMXUKGWMISQ-SECBINFHSA-N

Descrição geral

(R)-(−)-Carvone is a monoterpenoid. Its ozonolysis in the gaseous phase has been proposed. Aldehydes (formaldehyde) and biradicals were obtained as the major products.[1] It participates in the diastereoselective synthesis of homochiral octalones.[2]

Aplicação

(R)-(−)-Carvone may be employed as starting reagent for the synthesis of enantiopure (R)-(+)-3-methyl-6-isopropenyl-cyclohept-3-enone-1, a useful intermediate formed during the synthesis of terpenoids.[3] It may be employed as starting reagent for the synthesis of differently protected (4S,6R,7R)-trihydroxy-1-octyne derivatives.[4]

Chiral starting material.