4-Bromophenylboronic acid

≥95.0%

Sinônimo(s):

(p-Bromophenyl)boronic acid, 4-Bromobenzeneboronic acid, 4-Bromophenylboric acid, p-Bromobenzeneboronic acid, p-Bromophenylboric acid, NSC 25407

Sobre este item

Fórmula linear:

BrC₆H₄B(OH)₂

Número CAS:

5467-74-3

Peso molecular:

200.83

UNSPSC Code:

12352103

NACRES:

NA.22

PubChem Substance ID:

24892010

EC Number:

226-779-9

Beilstein/REAXYS Number:

2936347

MDL number:

MFCD00002104

InChI

1S/C6H6BBrO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H

InChI key

QBLFZIBJXUQVRF-UHFFFAOYSA-N

SMILES string

OB(O)c1ccc(Br)cc1

assay

≥95.0%, 95%

form

crystals

mp

284-288 °C (lit.)

Quality Level

200

Application

Reagent used for

• Palladium catalyzed Suzuki-Miyaura cross-couplings[1]
• Pd(II)-catalyzed diastereoselective conjugate additions[2]
• Palladium-catalyzed stereoselective Heck-type reaction of allylic esters with arylboronic acids[3]
• Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence[4]
• Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides[5]
• Pd-catalyzed arylative cyclization of alkyne-tethered enals or enones via carbopalladation of alkynes[6]
• Copper-catalyzed cross-couplings[7][8]

Reagent used in Preparation of

• Gallate-based obovatol analogs with potential anti-tumor activity[9]
• Protein modulators and enzymatic and kinase inhibitors[10][11]

Other Notes

Contains varying amounts of anhydride