P-Anisidine

99%

Sinônimo(s):

4-Aminoanisole, 4-Methoxyaniline

Fórmula linear:

CH₃OC₆H₄NH₂

Número CAS:

104-94-9

Peso molecular:

123.15

Beilstein:

471556

Número MDL:

MFCD00007864

ID de substância PubChem:

24891372

NACRES:

NA.22

Nível de qualidade

200

Ensaio

99%

forma

solid

temperatura de autoignição

959 °F

pb

240-243 °C (lit.)

pf

56-59 °C (lit.)

SMILES string

COc1ccc(N)cc1

InChI

1S/C7H9NO/c1-9-7-4-2-6(8)3-5-7/h2-5H,8H2,1H3

InChI key

BHAAPTBBJKJZER-UHFFFAOYSA-N

Aplicação

p-Anisidine can undergo aerobic oxidation in the presence of gold catalysts to form aromatic azo compounds.[1]
p-Anisidine can be used:

In the diastereoselective and enantioselective synthesis of CF₃-substituted azoridines catalyzed by a chiral Bronsted acid.[2]

To prepare 4-organoselenium-quinolines through multi-component Povarov reaction with ethyl glyoxylate and ethynyl(phenyl)selane, catalyzed by Yb(OTf)₃.[3]

As a starting material to synthesize 3-fluoro-6-methoxyquinoline in two steps.[4],

To prepare N-PMP protected α-aminopropargylphosphonates by reacting with terminal alkynes and diethyl formylphosphonate hydrate using silver(I) triflate as a catalyst.[5]